Both the LG OLED83C5PUA and Samsung QA83S95FAEXXY share a strong display foundation: identical 83.5″ OLED panels at 4K (3840 x 2160) resolution, a 53 ppi pixel density, 10-bit color depth rendering over a billion colors, and wide 178° viewing angles in both directions. For picture quality fundamentals, these two are essentially matched — both deliver the deep blacks and infinite contrast that OLED technology is known for.
The meaningful divergences emerge in three areas. First, refresh rate: the Samsung pulls ahead with a 165Hz panel versus the LG's 120Hz, which translates to noticeably smoother motion in fast-paced gaming and action content. Second, HDR ecosystem support splits them in opposite directions — the LG supports Dolby Vision but not HDR10+, while the Samsung supports HDR10+ but not Dolby Vision. In practice, this means content mastered for Dolby Vision (common on Apple TV+, Netflix) will look its best on the LG, while HDR10+ content (prevalent on Amazon Prime Video and Samsung's own ecosystem) favors the Samsung. Third, on adaptive sync, the LG adds Nvidia G-Sync compatibility alongside AMD FreeSync, making it the stronger pick for PC gamers with Nvidia GPUs, whereas the Samsung is limited to the AMD FreeSync stack (including FreeSync Premium Pro).
Overall, the Samsung holds a clear edge for high-refresh-rate gaming at 165Hz, and the two products split on HDR format allegiance rather than one being objectively superior. The LG, however, is the better fit for Nvidia GPU owners and households invested in the Dolby Vision content library. Your choice here should be driven by your primary use case: gaming frame rate and HDR10+ coverage favor the Samsung, while Nvidia PC gaming and Dolby Vision content favor the LG.