The most fundamental difference here is panel technology. The Philips 77OLED810/12 uses an OLED panel, where each pixel generates its own light and can switch off completely, producing true blacks and theoretically infinite contrast. The Samsung QN85QEF1AF relies on QLED LCD technology, which uses a quantum dot filter over an LED backlight — it delivers strong brightness but cannot match OLED's per-pixel light control. For dark room viewing or cinematic content, this distinction alone is significant.
On motion and HDR format support, the Philips pulls further ahead. Its 144Hz refresh rate versus the Samsung's 60Hz means noticeably smoother motion in fast-action content, sports, and gaming — 60Hz is a meaningful limitation by today's standards. The Philips also supports Dolby Vision, one of the most widely used dynamic HDR formats on streaming platforms, while the Samsung does not; both share HDR10, HDR10+, and HLG support. The Samsung's only tangible offset is its larger 84.5″ screen versus the Philips's 77″, which could matter in a large living room where raw screen real estate is the priority.
Overall, the Philips 77OLED810/12 holds a clear display advantage on the specs provided. OLED vs QLED, a higher refresh rate, and broader HDR format coverage are all meaningful real-world differences. The Samsung's larger screen size is the one area where it edges ahead, but users prioritizing picture quality, motion clarity, and HDR versatility will find the Philips the stronger performer based strictly on these specifications.