The most straightforward differentiator here is Android version: the Xiaomi 17 Pro Max ships with Android 16 while the S25 Ultra launches on Android 15. A newer OS version generally means access to the latest platform security patches, privacy framework improvements, and system-level features out of the box — a meaningful head start, even if Samsung's update cadence may eventually close the gap.
Digging into the feature-level differences, the S25 Ultra pulls ahead in a few practical areas. It supports cross-site tracking blocking (the Xiaomi does not), offers Wi-Fi password sharing for easy network handoff to nearby contacts, includes focus modes for distraction management, and — notably — supports desktop/PC mode, allowing it to be used as a productivity workstation when connected to a display. The Xiaomi, by contrast, lacks all four of these. On the flip side, the Xiaomi does not offer cross-site tracking blocking, which is a minor but real privacy gap compared to the S25 Ultra.
Weighing both sides, the S25 Ultra holds the stronger practical OS advantage despite running an older Android version. Its broader feature set — desktop mode, focus modes, Wi-Fi sharing, and cross-site tracking protection — addresses a wider range of real-world use cases. The Xiaomi's Android 16 base is a forward-looking plus, but the missing features represent tangible day-to-day gaps that tip this category toward Samsung.